Oxidative addition and reductive elimination are two important and related classes of reactions in organometallic chemistry.
1
The immediate product of the oxidative addition step is found to undergo facile reductive elimination to provide the arylation product.
2
The 1H NMR study indicated the reductive elimination of the p-toluenesulfonyl group from Ts-OF in the presence of antioxidants and photo-irradiation.
3
Electrons transferred from NADPH via cytosolic flavoprotein oxidoreductases are used to cleave the cobalt-carbon bond with reductive elimination of the cyanide ligand.
4
Using strategies based on enzymatic, chemical, and mass spectrometric analysis, we have defined the structures of the major glycans released by reductive elimination from GCX.
5
A highly reactive seven-membered Mn(I) intermediate is detected and characterized that is effective for H-transfer or reductive elimination to deliver alkenylated or pyridinium products, respectively.
1
This causes oxidative addition to become the rate-limiting step in the 1,10-phenanthroline-mediated reaction.
2
The immediate product of the oxidative addition step is found to undergo facile reductive elimination to provide the arylation product.
3
It is suggested that the formation of a T-shaped intermediate could foster the C-H activation via oxidative addition to the metal centre.
4
Because O-coordination of a deprotonated amino alcohol is favored over N-coordination in the oxidative addition transition state, O-arylation is favored with the 1,10-phenanthroline ligand.